[eluser]Sander Versluys[/eluser]
First problem had todo with my fresh install of xampp which comes with PHP 5.3. This caused set_date_timezone errors because php from now on requires you to explicitly set the timezone. So i included this after the error_reporting line in the index.php file.
Second xampp doesn't enable mysqli by default and/or was not able to get the right setting out of the box. After trying some tweaking of the php.ini files I uninstalling xampp and went back to an older version, on which CI runs fine now. I initially lost to much time to really dig into it...