[eluser]adamck[/eluser]
You would have to use some other software (possibly C#) to take the snapshots and upload them for you to do this.
If you could take snapshots of peoples desktops via PHP... every hacker/spammer in the world would be snooping on people as soon as they visited their website...
You might be able to write an IE / FireFox plugin to work with your script.... could work... but the user would have to install the plugin for it to work etc...
I doubt you will get this working though, its a HUGE security issue if the user isnt aware the screenshots are happening etc...