[eluser]mistersmith[/eluser]
What I did in the end:
I put a file on the root of the server that declares a single associative array with my custom settings in it.
Added a "require" to the top of my config/config.php file, and stored the associative array from that file in the standard CodeIgniter config array:
require('config'.EXT);
$config['custom_settings'] = $custom_settings;
Then, later in my app, inside Models or Controllers, I can access those settings with:
$custom_settings = $this->config->item('custom_settings');
$some_val = $custom_settings['some_key'];
Inside Libraries, however, I needed to do it this way:
$ci =& get_instance();
$custom_settings = $ci->config->item('custom_settings');
$some_val = $custom_settings['some_key'];
It'll have to do for now I suppose